Synthesis zeolitic Imidazolate Framework-8 (Zif-8) In Solvothermal: The Effect Comparison of Metal-Ligand

  • Muhammad Nadjib Jurusan Kima Institut Teknologi Sepuluh Nopember, Surabaya
  • Ratna Ediati Jurusan Kima Institut Teknologi Sepuluh Nopember, Surabaya
  • Yudi Aris Sulistiyo Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Jember, Jember
  • Lutfiatun Nadifah Jurusan Kima Institut Teknologi Sepuluh Nopember, Surabaya
DOI: https://doi.org/10.19184/jid.v17i1.2674

Abstract

Synthesis of ZIF-8 (zeolitic Imidazolate Frameworks-8) have been successfully carried out by the reaction of zinc nitrate and 2-methylimidazolate in DMF (N'N-dimethylformamide) solvent at a temperature of 120 °C for 24 hours. Synthesis of ZIF-8 has been conducted five times with variations molar ratio of metal (Zn2+):ligand (MeIM) consecutive 1:1; 1:1.5; 1:2; 1:2.5 and 1:3 to study the influence of metal-ligand ratio of the crystallinity and morphology of ZIF-8 that was produced. The results of characterization by X-ray diffraction, FTIR and SEM show that ZIF-8 is synthesized with a ratio of metal: ligand = 1:2 showed the highest crystallinity and has the most irregular surface morphology with form box.

Keywords: ZIF-8, solvotermal, metal/ligand ratio

 

Published
2017-01-24
How to Cite
NADJIB, Muhammad et al. Synthesis zeolitic Imidazolate Framework-8 (Zif-8) In Solvothermal: The Effect Comparison of Metal-Ligand. Jurnal ILMU DASAR, [S.l.], v. 17, n. 1, p. 53-58, jan. 2017. ISSN 2442-5613. Available at: <https://jurnal.unej.ac.id/index.php/JID/article/view/2674>. Date accessed: 20 apr. 2024. doi: https://doi.org/10.19184/jid.v17i1.2674.
Citation Formats
Issue
Vol 17 No 1 (2016)
Section
General